Solid-phase Microextraction (SPME) with Stable Isotope Calibration for Measuring Bioavailability of Hydrophobic Organic Contaminants
نویسندگان
چکیده
منابع مشابه
Calibration of a commercial solid-phase microextraction device for measuring headspace concentrations of organic volatiles.
Solid-phase microextraction (SPME) is a versatile new technique for collecting headspace volatiles prior to GC analysis. The commercial availability of uniform SPME fibers makes routine, practical quantitation of headspace concentrations possible, but straightforward information for relating GC peak areas from SPME analyses to headspace concentrations has not been available. The calibration fac...
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Sediment quality assessment is often hindered by the lack of agreement between chemical and biological lines of evidence. One limitation is that the bulk sediment toxicant concentration, the most widely used chemical parameter, does not always represent the bioavailable concentration, particularly for hydrophobic organic compounds (HOCs) in highly contaminated sediments. In this study, a porewa...
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Sediment-quality assessment often is hindered by the lack of agreement between chemical and biological lines of evidence. One limitation is that the bulk sediment toxicant concentration, the most widely used chemical parameter, does not always represent the bioavailable concentration, particularly for hydrophobic organic compounds (HOCs) in highly contaminated sediments. In the present study, w...
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The elevated occurrence of hydrophobic organic chemicals (HOCs) such as polycyclic aromatic hydrocarbons (PAH), polychlorinated biphenyls (PCBs) and legacy organchlorine pesticides (e.g. chlordane and DDT) in estuarine sediments continues to poses challenges for maintaining the health of aquatic ecosystems. Current efforts to develop and apply protective, science-based sediment quality regulati...
متن کاملPreparation of Solid Phase Microextraction (SPME) Probes through Polyaniline Multiwalled Carbon Nanotubes (PANI/MWCNTs) Coating for the Extraction of Palmitic Acid and Oleic Acid in Organic Solvents
A fiber coating from polyaniline (PANI) was electrochemically prepared and employed for Solid phase micreoextraction (SPME). The PANI film was directly electrodeposited on the platinum wire surface using cyclic voltametry (CV) technique. The same method was applied for the preparation of SPME fiber coated by polyaniline multiwalled carbon nanotubes (PANI/MWCNTs) composite. The concentration of ...
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ژورنال
عنوان ژورنال: Environmental Science & Technology
سال: 2013
ISSN: 0013-936X,1520-5851
DOI: 10.1021/es4022987